活性烯烃聚合综述（文献）
在读Coates刚发在OL上的一篇文章，顺便去查查Web of Science时，无意之中发现这篇文章。之所以感兴趣，一方面这是烯烃活性聚合的综述；另一方面文章第一作者是我曾经带过的大学生。更重要的是，国内目前搞烯烃聚合的组很多，对这样的方向会有所感兴趣。内容我就不叙述了。关键词也就说明了问题：
Title: [b]Living alkene polymerization: New methods for the precision synthesis of polyolefins[/b]
Author(s): [url=http://apps.isiknowledge.com/WoS/CIW.cgi?SID=1C1Bd8jooOIa4Mabbke&Func=OneClickSearch&field=AU&val=Domski+GJ&ut=000244408900002&auloc=1&fullauth= (Domski, Gregory J.)&curr_doc=2/11&Form=FullRecordPage&doc=2/11][color=#0000ff]Domski GJ[/color][/url] (Domski, Gregory J.), [url=http://apps.isiknowledge.com/WoS/CIW.cgi?SID=1C1Bd8jooOIa4Mabbke&Func=OneClickSearch&field=AU&val=Rose+JM&ut=000244408900002&auloc=2&fullauth= (Rose, Jeffrey M.)&curr_doc=2/11&Form=FullRecordPage&doc=2/11][color=#0000ff]Rose JM[/color][/url] (Rose, Jeffrey M.), [url=http://apps.isiknowledge.com/WoS/CIW.cgi?SID=1C1Bd8jooOIa4Mabbke&Func=OneClickSearch&field=AU&val=Coates+GW&ut=000244408900002&auloc=3&fullauth= (Coates, Geoffrey W.)&curr_doc=2/11&Form=FullRecordPage&doc=2/11][b][color=#0000ff]Coates GW[/color][/b][/url] (Coates, Geoffrey W.), [url=http://apps.isiknowledge.com/WoS/CIW.cgi?SID=1C1Bd8jooOIa4Mabbke&Func=OneClickSearch&field=AU&val=Bolig+AD&ut=000244408900002&auloc=4&fullauth= (Bolig, Andrew D.)&curr_doc=2/11&Form=FullRecordPage&doc=2/11][color=#0000ff]Bolig AD[/color][/url] (Bolig, Andrew D.), [url=http://apps.isiknowledge.com/WoS/CIW.cgi?SID=1C1Bd8jooOIa4Mabbke&Func=OneClickSearch&field=AU&val=Brookhart+M&ut=000244408900002&auloc=5&fullauth= (Brookhart, Maurice)&curr_doc=2/11&Form=FullRecordPage&doc=2/11][color=#0000ff]Brookhart M[/color][/url] (Brookhart, Maurice)
Source: PROGRESS IN POLYMER SCIENCE 32 (1): 30-92 JAN 2007
Document Type: Review
Language: English
[url=http://apps.isiknowledge.com/WoS/CIW.cgi?SID=1C1Bd8jooOIa4Mabbke&Func=PagedCitedRefList&UT=000244408900002&doc=2/11&rec_id=154874947][color=#0000ff][b]Cited References:[/b] 210[/color][/url] [url=http://apps.isiknowledge.com/WoS/CIW.cgi?SID=1C1Bd8jooOIa4Mabbke&Func=DispCitingRec&doc=2/11&isickref=154874947][color=#0000ff][b]Times Cited:[/b] 13[/color][/url]
Abstract: Precise control over product structure is the goal of all chemical synthesis. In the field of polymer synthesis, the structure of the resultant macromolecule is intimately linked to its material properties, which ultimately determines the potential applications for the polymeric material. Method development for alkene polymerization is becoming increasingly focused on achieving fine control over all aspects of macromolecular architecture; especially chain composition, molecular weight, and stereochemistry.
One of the most powerful methods developed so far which is capable of furnishing a high degree of control over polymer architecture is living alkene polymerization catalyzed by transition metal complexes. Living polymerization is characterized by efficient initiation and chain termination/transfer rates that are negligible in comparison to the rate of propagation. Using living alkene polymerization methods, polymer chemists have synthesized materials with microstructures that were inaccessible just a decade ago. Specific examples include polyolefin-based block copolymers, end-functionalized polyolefins, and stereo/regioblock copolymers with well-defined block structures.
This review is a comprehensive account of living alkene polymerization systems with special attention paid to systems developed in the last 5 years. The text is organized by polymer type, which will allow those seeking to construct a specific polymer architecture to quickly identify relevant methodologies. (c) 2006 Elsevier Ltd. All rights reserved.
Author Keywords: alkenes; polyolefins; block copolymers; living polymerization; homogeneous catalysis; stereoblock copolymer
[[i] 本帖最后由 agostic 于 2007-12-21 22:00 编辑 [/i]]
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