☆麦兜☆ » ASAP_Paper_Show_捷报频传 » [Inorg. Chem.] Assembly of the Highest Connectivity Wells-Dawson Polyoxometalate Coordination Polymer: the Use of Organic Ligand Flexibility

yingj808 发表于 2008-3-26 12:31

[Inorg. Chem.] Assembly of the Highest Connectivity Wells-Dawson Polyoxometalate Coordination Polymer: the Use of Organic Ligand Flexibility

Authors:Ai-xiang Tian,† Jun Ying,† Jun Peng,*† Jing-quan Sha,† Zhan-gang Han,† Jian-fang Ma,† Zhong-min Su,† Ning-hai Hu,‡ and Heng-qing Jia‡

Web Release Date:March 11, 2008

DOI:  10.1021/ic7023082

Abstract:Through tuning the length of flexible bis(triazole) ligands and different metal ion coordination geometries, four Wells-Dawson polyoxoanion-based hybrid compounds, [Cu6(btp)3(P2W18O62)]·3H2O (1) (btp = 1,3-bis(1,2,4-triazol-1-y1)propane), [Cu6(btb)3((P2W18O62)]·2H2O (2), [Cu3(btb)6(P2W18O62)]·6H2O (btb = 1,4-bis(1,2,4-triazol-1-y1)butane) (3), and [Cu3(btx)5.5((P2W18O62)]·4H2O (btx = 1,6-bis(1,2,4-triazol-1-y1)hexane) (4), were synthesized and structurally characterized. In compound 1, the metal-organic motif exhibits a ladder-like chain, which is further fused by the ennead-dentate [P2W18O62]6− anions to construct a 3D structure. In compound 2, the metal-organic motif exhibits an interesting Cu−btb grid layer, and the ennead-dentate polyoxoanions are sandwiched by two Cu−btb layers to construct a 3D structure. Compound 3 exhibits a (42·62·82) 3D Cu−btb framework with square and hexagonal channels arranged alternately. The hexa-dentate polyoxoanions incorporate only into the hexagonal channels. In compound 4, there exist two sets of (61·102)2(61·82·103) 3D Cu−btx frameworks to generate a 2-fold interpenetrated structure into which the penta-dentate polyoxoanions are inserted to construct a 3D structure. The structural analyses reveal that the length of flexible bis(triazole) ligands and metal ion coordination geometries have a synergic influence on the structures of this series. To our knowledge, they have the highest connectivity for the Wells-Dawson polyoxometalate coordination polymers to date.

Link:[url]http://pubs.acs.org:80/cgi-bin/abstract.cgi/inocaj/asap/abs/ic7023082.html[/url]

sally208 发表于 2008-3-26 13:32

恭喜楼主！ ：）

cc136520 发表于 2008-3-26 15:05

很漂亮的结构,期待楼主分享文章后面的故事

Metalcarbene 发表于 2008-3-26 17:58

回复 1楼的 yingj808 的帖子

俺也恭喜下:lol

qingjiaokong 发表于 2008-3-28 09:05

恭喜啊~
真是羡慕啊~

liqiong29 发表于 2008-8-26 11:47

回复 5# qingjiaokong 的帖子

请问楼主，当初投稿时选择4个审稿人怎么选？小弟如今正在投，遇到这个问题。还请楼主指教，谢谢了！

citric 发表于 2008-8-27 02:47

恭喜呀, 什么时候我也会做这么好的结构就好啦!

ypp5181 发表于 2008-8-28 00:33

恭喜恭喜！:) :) :)

zjniu 发表于 2008-9-3 16:41

恭喜恭喜

churen 发表于 2008-9-4 07:27

回复 1# yingj808 的帖子

nice

jssxh 发表于 2008-9-4 08:03

:P :P :P :P :P :P :P :P :P

dreamwalk 发表于 2008-9-4 12:04

恭喜楼主！ ：）

dwmchem 发表于 2008-9-18 09:15

不错不错！学习了！！！

chemldang 发表于 2008-9-19 10:18

回复 2# sally208 的帖子

congratulation

chenshuuu 发表于 2008-9-20 20:21

分享感受最好

chemldang 发表于 2008-9-21 15:09

回复 1# yingj808 的帖子

恭喜

hnlj 发表于 2008-9-28 08:56

恭喜楼主！

恭喜楼主！ ：）

hqzhang 发表于 2008-9-29 15:32

恭喜楼主！不过我觉得这些晶体似乎用处不大
[color=red][fbox=Random Bonus]Congratulations to hqzhang, who obtained 1 token(s) from the system by replying to this thread.[/fbox][/color]

xinli 发表于 2008-9-29 16:58

恭喜楼主
羡煞旁人啊

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