有机所枫林论坛第四期(庆五一)
【Speaker】 胡金波 研究员【Affiliation】sioc
【Time】2007年
【Venue】
【Abstract】我的研究生经历
【Fulltext】[url]http://www.box.net/shared/lqk069eokk[/url]
【Others】
SIOC address is fenglin 354
1973 出生于浙江
1990－1994 杭州大学化学系化学专业，本科
(有机化学专门化班）
1994－1997 中科院上海冶金所
材料化学专业，硕士
1997－2002 美国南加州大学化学系，博士
有机化学专业(Olah)
2002－2005 美国南加州大学碳氢化学研究所
博士后
2005－至今 上海有机所工作
Summary of Ph.D. Research Work
Facile preparation of di- and monofluoromethyl ketones from trifluoromethyl
ketones via an selective defluorination
Preparation of 18F labeled trifluoromethyl ketones and other
halodifluoromethyl ketones via selective halogenation of 2,2-difluoro
enol silyl ethers
Preparation of trifluoromethyl- and difluoromethylsilanes via an
unusual magnesium metal mediated reductive tri- and
difluoromethylation
Novel alkoxide induced nucleophilic tri- and difluoromethylation
using tri- and difluoromethyl sulfones or sulfoxides
Synthesis of partially fluorinated ethers by alkylation of in situ generated
fluorinated alkoxides from fluoroacyl halides and the fluoride ion
Synthesis of fluorinated carbonates, carbamates and other polymeric
materials for low temperature lithium-ion battery applications
New synthesis of superacidic fluorinated sulfonic acids (ClCF2SO3H,
PhCF2CF2SO3H, solid acids, etc.) as potential acid catalysts and
fuel cell membrane materials
Development of a new metal-free anionic polymerization initiating
system using organosilane/fluoride (such as Ph3CSiMe3/Me4NF).
MMA was polymerized by this system to give > 95 % yield of PMMA
with Mn = 96,000 and PDI = 1.04. 羡慕ing;P ;P ;P
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