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zgxue2001 发表于 2008-7-16 14:46

Angew - Phosphorus-Containing Ligands for Iron(III)-Catalyzed Atom Transfer Radical Polymerization

Authors: [u][color=Black]Zhigang Xue[/color][/u], Nguyen Thuy Ba Linh, Seok Kyun Noh, Won Seok Lyoo

Published Online: 15.07.2008   DOI: 10.1002/anie.200801647

Abstract: Living polymers: Iron(III) complexes with phosphorus-containing ligands are efficient catalysts for atom transfer radical polymerization in the absence of any radical initiator or reducing agent. The polymers produced have good molecular weights and narrow polydispersities as determined by gel permeation chromatography (see scheme). The controlled nature of the FeBr3/dppp system was confirmed by a chain-extension experiment. Mn,GPC in [gmol1].
Keywords: iron • ligands • polymers • radical reactions

Link: [url]http://www3.interscience.wiley.com/journal/120776001/abstract?CRETRY=1&SRETRY=0[/url]
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myheric 发表于 2008-7-16 15:37

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cc136520 发表于 2008-7-16 16:58

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asymmsyn 发表于 2008-7-16 19:00

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qingjiaokong 发表于 2008-7-16 19:48

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Metalcarbene 发表于 2008-7-16 20:44

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sally208 发表于 2008-7-17 12:56

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tpy60 发表于 2008-7-18 00:07

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yushouyun 发表于 2008-7-18 00:54

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