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yan123 发表于 2008-7-19 03:16

Regioselective Zirconophosphination of 1-Alkenes

Regioselective Zirconophosphination of 1-Alkenes: A Versatile Route for the Synthesis of β-Functionalized Alkyldiphenylphosphine Oxides in the Presence of CuCl
Chanjuan Xi,*† Xiaoyu Yan,† Chunbo Lai,† Ken-ichiro Kanno,‡ and Tamotsu Takahashi‡
Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084, People's Republic of China, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, People's Republic of China, and Catalysis Research Center, Graduate School of Pharmaceutical Sciences, Hokkaido University, Sapporo 001-0021, Japan
Received December 17, 2007
[img]http://pubs.acs.org/isubscribe/journals/orgnd7/asap/figures/om-2007-01253d_0001.gif[/img]

Abstract:
Zirconocene−alkene complexes Cp2Zr(PMe3)(CH2CHR) reacted with chlorodiphenylphosphine to form zircono-ethylphosphine derivatives with high regioselectivity, which could be converted into various β-functionalized alkyldiphenylphosphine oxides in the presence of CuCl.

[url]http://pubs.acs.org/cgi-bin/abstract.cgi/orgnd7/asap/abs/om701253d.html[/url]

myheric 发表于 2008-7-19 08:54

恭喜恭喜！

asymmsyn 发表于 2008-7-19 08:56

恭喜恭喜！

Metalcarbene 发表于 2008-7-19 10:16

Congratulations

tpy60 发表于 2008-7-22 01:10

congratulation

hattoriheji 发表于 2008-7-23 19:08

呵呵 昨天就打下来这篇paper了

yanqiang 发表于 2008-7-24 07:59

何必呢...呵呵...

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