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ndcat 发表于 2008-7-23 06:19

Cationic oxorhenium chiral salen complexes for asymmetric hydrosilylation and kinetic resolution of alcohols

Guodong Du, Phillip E. Fanwick, Mahdi M. Abu-Omar

Graphical abstract
A series of cationic oxorhenium (V) chiral salen complexes, including a rare trinuclear rhenium species, have been prepared and fully characterized. These compounds are found to be effective for catalytic hydrosilylation of ketones and silane alcoholysis. The reaction mechanism is discussed in light of an isolated intermediate and a crossover experiment.

Metalcarbene 发表于 2008-7-23 17:50

Welcome new QM from Purdue Univ.

tpy60 发表于 2008-7-24 01:52

welcome new QM

cc136520 发表于 2008-7-24 14:09

welcome

supra 发表于 2008-7-25 10:43

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