☆麦兜☆ » ASAP_Paper_Show_捷报频传 » 【J. Phys. Chem. B】Hyperbranched Ferrocenyl Polymer Film with High Charge Transport Efficiency

hjlyyc 发表于 2008-8-29 15:53

【J. Phys. Chem. B】Hyperbranched Ferrocenyl Polymer Film with High Charge Transport Efficiency

放假回了，发现文章刚刚正式发表，虽然一般，也是俺最好的啦！哈哈
Authors:
[b]Jia Huo,[/b] [b]Li Wang[/b][b],et al.[/b]
Web Release Date:
August 22, 2008
DOI:
10.1021/jp7121888
Abstract:
The electrochemical behaviors of hyperbranched poly(ferrocenyl-methylsilane) (HPFMS) and linear oligo(ferrocenyldimethylsilane) (LOFS) films were studied systematically by cyclic voltammetry and chronocoulometry under different polymer coverage and solvents. Both poly(ferrocenylsilanes) show stable cyclic voltammographs in LiClO4 solutions. Compared with LOFS films, HPFMS films exhibit higher charge transport efficiency because of their hyperbranched structure: peak current ([i]i[/i]p) and apparent diffusion coefficient ([i]D[/i]app) for HPFMS films are larger than those for LOFS films, especially at high polymer coverage (3.8 × 10−11 vs 3.9 × 10−12 cm2/s for HPFMS and LOFS film at the coverage of 2.1 × 10−6 mol Fc/cm2). The conceptual models of electrode processes for HPFMS and LOFS films were proposed to account for higher charge transport efficiency of HPFMS films. It is also found that a solvent with the appropriate solubility parameter and polarity, lower viscosity, and higher dielectric constant is in favor of charge transport through polymer films, which is consistent with the proposed model of electrode process for HPFMS films. These results imply that hyperbranched ferrocenyl polymers have the potential to be excellent chemical sensor materials with convenient synthesis and high sensitivity.
Link:
[url=http://pubs.acs.org/cgi-bin/abstract.cgi/jpcbfk/asap/abs/jp7121888.html]http://pubs.acs.org/cgi-bin/abstract.cgi/jpcbfk/asap/abs/jp7121888.html[/url]
:victory: :victory:
[color=red][fbox=Random Bonus]Congratulations to hjlyyc, who obtained 1 token(s) from the system by posting this thread.[/fbox][/color]

myheric 发表于 2008-8-29 16:24

恭喜！

逐水流云 发表于 2008-8-29 16:53

恭喜！~

liutao_jlu 发表于 2008-8-29 17:14

:handshake :handshake
恭喜

cc136520 发表于 2008-8-29 18:05

祝贺一下

sally208 发表于 2008-8-29 18:49

恭喜楼主了！:)

Sunlit 发表于 2008-8-29 18:59

过度的谦虚是骄傲的凸现

wzyan 发表于 2008-8-29 19:20

恭喜啊

hjlyyc 发表于 2008-8-29 20:18

回复 7# Sunlit 的帖子

主要是chem8上牛人实在太多，所以要低调做人啊！:handshake

mcri 发表于 2008-8-29 20:22

goodd!!!!!!!!!

zjniu 发表于 2008-8-29 20:36

恭喜

citric 发表于 2008-8-29 22:48

工作量很大,  祝贺!

Metalcarbene 发表于 2008-8-29 23:54

回复 1# hjlyyc 的帖子

恭喜恭喜:)

yuancs 发表于 2008-8-30 00:39

恭喜

xzhdty 发表于 2008-8-30 07:10

恭喜恭喜

weihui_cn 发表于 2008-8-30 07:52

:victory: :victory: :victory:

rhzhang 发表于 2008-8-30 10:47

恭喜

yeqs1 发表于 2008-8-30 12:16

恭喜兄弟                        
:victory:

arimpt 发表于 2008-8-30 17:09

:P :P :P 祝贺祝贺

hjlyyc 发表于 2008-8-30 23:17

回复 12# citric 的帖子

做的比较基础，条件做了较多，兄弟见笑

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