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Title:
Organic Solid State Reactions (Topics in Current Chemistry V254) |
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Division: Methods, Synthesis & Techniques / Springer / 英文版 |
Author/Editor: Fumio Toda(Editor) Star:  |
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ISBN: 3540229825 |
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Introduce Date: 2006年08月28日03:07 , Release Date: 2006年08月28日13:29 |
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Introducer: paracyclophane , Rate: 1/116 |
| Format: pdf(editorial) Download |
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| Description: |
Organic Solid State Reactions
Book Series Topics in Current Chemistry
Publisher Springer Berlin / Heidelberg
ISSN 0340-1022 (Print) 1436-5049 (Online)
Subject Chemistry and Materials Science
Volume Volume 254/2005
DOI 10.1007/b98357
ISBN 978-3-540-22982-7/3540229825
Online Date Thursday, March 10, 2005
Most organic reactions have long been carried out in organic solvents without concern for their real necessity, reaction efficiency, and pollution problems. Very recently, we have found that most organic reactions can be carried out in the absence of a solvent, namely, in the solid state. In many cases, the solid-state reaction proceeds more easily and efficiently, and even more selectively than solution reaction. This shows that molecules move easily and selectively in the solid state. This finding changed the classical idea which suggests "molecules do not move and reactions do not occur in the solid state", and opened up a new research field for the study molecular dynamics in the solid state. The organic solid state reactions have many possibilities to be developed. For example, enantioselective reactions can easily be accomplished by carrying out the reaction in an inclusion complex crystal with an optically active host compound. Catalytic reactions also proceed in the solid state. Moreover, the solid-state reactions are more economical and ecologically sound. In the future, pollution-free synthetic procedures in the solid state will become increasingly important, not only in chemical industries but also in university laboratories.
Front Matter
Text PDF (134 kb)
Thermal and Photochemical Reactions in the Solid State
DOI 10.1007/b100994
Author Fumio Toda
Text PDF (584 kb)
1-40
Crystal Engineering of Organic Cocrystals by the Solid-State Grinding Approach
DOI 10.1007/b100995
Authors Andrew V. Trask and William Jones
Text PDF (819 kb)
41-70
Intra-Solid and Inter-Solid Reactions of Molecular Crystals: a Green Route to Crystal Engineering
DOI 10.1007/b100996
Authors Dario Braga, Daniela D’Addario, Stefano L. Giaffreda, Lucia Maini, Marco Polito and Fabrizia Grepioni
Text PDF (606 kb)
71-94
Organic Solid-State Reactions with 100% Yield
DOI 10.1007/b100997
Author Gerd Kaupp
Text PDF (1,675 kb)
95-183
kThe Mechanochemical Solid-State Reaction of Fullerenes
DOI 10.1007/b100998
Author Koichi Komatsu
Text PDF (520 kb)
185-206
Photochemical Aspects of Thiocarbonyl Compounds in the Solid-State
DOI 10.1007/b100999
Author Masami Sakamoto
Text PDF (575 kb)
207-232
Asymmetric Induction in Organic Photochemistry via the Solid-State Ionic Chiral Auxiliary Approach
DOI 10.1007/b101000
Authors John R. Scheffer and Wujiong Xia
Text PDF (474 kb)
233-262
Reactions of 1,3-Diene Compounds in the Crystalline State
DOI 10.1007/b101001
Author Akikazu Matsumoto
Text PDF (892 kb)
263-305
Back Matter
Text PDF (131 kb)
http://www.springerlink.com/cont ... c6b9cbcaf&pi=11
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