Solid–vapor reaction properties of copper(II) and cadmium(II) sulfonates with amines
分类信息 - Paper认证
| 姓名 |
Liu PIng |
| 所在学校或单位 |
Sun Yat-Sen University |
| 文章题目 |
Solid–vapor reaction properties of copper(II) and cadmium(II) sulfonates with amines |
| 期刊名 |
Polyhedron |
| 年份，卷（期），起止页码 |
2006, 25(15), 3045-3052 |
| 影响因子 |
1.957 |
| 文章链接 |
http://dx.doi.org/10.1016/j.poly.2006.05.008 |
Abstract
The solid–vapor reaction properties of three transition metal sulfonates and amines were investigated and the reaction products were characterized by EA, TGA, IR, PXRD and single crystal structure analyses. [Cu(1,5-nds)(H2O)4]n (I), [Cu(H2O)6](1,5-nds) (II) (1,5-nds = 1,5-naphthalenedisulfonate) and [Cd(p-NH2C6H4SO3)2] (III) can react with primary alkyl amine vapors and form stable monoamine-coordinated Cu(II) and Cd(II) complexes. All of the amine adducts are crystalline materials. The reactions between [Cd(p-NH2C6H4SO3)2] (III) and C2H5NH2 or n-C3H7NH2 produced single crystals in situ via the solid–vapor reaction process.
Article Outline
1. Introduction
2. Experimental
2.1. Materials and methods
2.2. Syntheses of compounds I, II and III
2.3. Solid–vapor reaction
2.4. Characterization
2.5. X-ray structure analysis
3. Results and discussion
3.1. Syntheses and characterization
3.2. Reaction selectivity and preference
3.3. Crystal structure of [Cd(n-C3H7NH2)4(H2O)2](p-H2NC6H4SO3)2
4. Summary
5. Supplementary data
Acknowledgements
References
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Copper Sulfonate Cadmium Alkyl amine
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