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Self-Assembled Nano Ring Structures

Self-Assembled Nano Ring Structures

How are these ring structures formed? What is the driving force for these curved structures? Is there any common feature for the following structures with diverse chemical origins (including inorganic and organic compounds, polyelectrolytes, bundled CNT)?


Science, 2004, 303, 1348.
Single-Crystal Nanorings Formed by Epitaxial Self-Coiling of Polar nanobelts
Xiang Yang Kong, Yong Ding, Rusen Yang, Zhong Lin Wang



Single-Crystal Nanorings
The most common nano-structures are nanotubes and nanowires, but researchers have also created other nano-structures - such as these 'nanorings'. Nanorings of zinc oxide can form spontaneously under certain conditions. Electrostatic forces seem to cause a nanobelt to curve, while short range chemical bonding fuses the end, creating a single crystal ring. Zinc oxide nanorings formed by self-coiling of nanobelts may be useful in research and in the production of nanoscale devices.

Solid State Communications 2004, 131, 435.
Synthesis, structure, and photoluminescence of Zn2SnO4 single crystal nanobelts and nanorings
Xie, S. S. et al.



J. Am. Chem. Soc. 2006, 128, 1466. DOI: 10.1021/ja0578000
Springs, Rings, and Spirals of Rutile-Structured Tin Oxide Nanobelts
Rusen Yang and Zhong Lin Wang



Adv. Mater. 1998, 10, 351.
Surprising Superstructures: Rings
Tobias Vossmeyer, Sung-Wook Chung, William M. Gelbart, and James R. Heath


A: carbon nanotube rings (P. McEuen, personal communication, 1997)
B: nanocrystal rings (Heath, J. R. et al. Angew. Chem. Int. Ed. Engl. 1997, 36, 1078.)
C: porphyrin rings (Nolte, R. J. M. et al. J. Am. Chem. Soc. 1996, 118, 8549.)


A: rings of single-walled carbon nanotube bundles (Smalley, R. E. et al. Nature 1997, 385, 780)
B: coils of single-walled carbon nanotube bundles (Avouris, P. et al. Nature 1999, 398, 299)
C: rings and coils of double-walled carbon nanotube bundles (Colomer, J.-F. et al. Nano Lett. 2003, 3, 685)
D: rings of carbon nanotubes aligned in adirection normal to the substrate surface (Dai L. M. et al. J. Mater. Chem. 1999, 9, 1221.)

Large-Scale Synthesis of Rings of Bundled Single-Walled Carbon Nanotubes by Floating Chemical Vapor Deposition
Adv. Mater. 2006, 18, 1817-1821.
L. Song, L. J. Ci, L. F. Sun, C. Jin, L. Liu, W. Ma, D. Liu, X. Zhao, S. Luo, Z. Zhang, Y. Xiang, J. Zhou, W. Zhou, Y. Ding, Z. L. Wang, S. Xie

J. Phys.: Condens. Matter 2004, 16, S210.
Self-assembled polyelectrolyte nanorings observed by liquid-cell AFM
J-Luis Menchaca, Hector Flores, Frederic Cuisinier and Elias Perez


A: PEI–PSS layer
B: PEI–PSS-PAH layer
Ring structure formed by PEI–PSS is kept when the PAH polyelectrolyte is injected. ring dimensions change due to the third polyelectrolyte (image: 5 × 5 µm; z range: 10 nm).


J. Phys. Chem. B 2006, 110, 6432.
Block-Copolymer-Controlled Growth of CaCO3 Microrings
Yun-Xiang Gao, Shu-Hong Yu, Huaiping Cong, Jun Jiang, An-Wu Xu, W. F. Dong, and Helmut Colfen



J. Am. Chem. Soc. 2005, 127, 18262. DOI: 10.1021/ja055734w
Semiconductor Rings Fabricated by Self-Assembly of Nanocrystals
Bin Liu and Hua Chun Zeng



Adv. Mater. 2005, 17, 1781.
Synthesis and Photoluminescence of SnO2/SiO2 Microrings
X. An, G. W. Meng, Q. Wei, X. Zhang, Y. Hao, L. D. Zhang


本帖最近评分记录
  • Mcdull 在2006-8-10 23:58 评分: 金币 +20 原因: Thx for preparing such a good topic!
  • Dice 在2006-8-3 23:54 评分: 金币 +5 原因: Nice!
  • choscar 在2006-8-1 20:40 评分: 金币 +5 原因: Good Topic and colloctions, but I am a layman in this area!
  • westwolf 在2006-8-1 18:13 评分: 金币 +5 原因: 非常有趣的话题,楼主化了不少时间整理这些资料.

TOP

不错,先占个沙发,等待讨论!

Very interesting topic! It more involves material science. I am a layman too. I have just read part of the references. About the first two questions, we may find clues from the papers. I am very curious about the answer forthe last question: what's the common feature of them? Anybody can give some clue?

TOP

Most of them are at micro scale. Is it possible to reduce the size?

Any special properties for these nanostructures?

It also remind me the nanoscrolls of VOx. Unfortunately I am not an expert in this field.

TOP

yes,discussation is necessary

重剑无锋,大巧不工。
谢谢分享

thx

赞一个先

慢慢研究一下,多谢先。

回复 #1 Reuben 的帖子

本人想通过嵌段共聚物或者纳米粒子自组装得到这中结构,怎么样啊

每人伸出一根手指,共同撑起chem8.
Nanorings from the Self-Assembly of Amphiphilic Molecular Dumbbells
Jung-Keun Kim, Eunji Lee, Zhegang Huang, and Myongsoo Lee
J. Am. Chem. Soc.; 2006; 128(43) pp 14022 - 14023; (Communication) DOI: 10.1021/ja065487b



Toroidal Triblock Copolymer Assemblies
Darrin J. Pochan, Zhiyun Chen, Honggang Cui, Kelly Hales, Kai Qi, and Karen L. Wooley
Science 2004 306: 94-97 [DOI: 10.1126/science.1102866] (in Reports)



Crystal topology: A Möbius strip of single crystals
Satoshi Tanda, Taku Tsuneta, Yoshitoshi Okajima, Katsuhiko Inagaki, Kazuhiko Yamaya and Noriyuki Hatakenaka
Nature 2002, 417, 397–398. doi:10.1038/417397a



Rings of Nanorods
Bishnu P. Khanal, Eugene R. Zubarev
Angewandte Chemie International Edition Volume 46, Issue 13, 2007, Pages: 2195-2198

引用:
原帖由 wzh12020915 于 2007-6-15 10:54 发表
本人想通过嵌段共聚物或者纳米粒子自组装得到这中结构,怎么样啊

本帖最近评分记录
  • choscar 在2007-6-15 12:42 评分: 金币 +20 原因: 原创内容
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